Yazar "0000-0002-0618-1979" için Scopus İndeksli Yayınlar Koleksiyonu listeleme
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Anhydrous proton conducting poly(vinyl alcohol) (PVA)/ poly(2-acrylamido-2-methylpropane sulfonic acid) (PAMPS)/1,2,4-triazole composite membrane
Erkartal, Mustafa; Aslan, Ayse; Erkilic, Ufuk; Dadi, Seyma; Yazaydin, Ozgur; Usta, Hakan; Sen, Unal (Elsevier Ltd, 2016)The design and fabrication of anhydrous proton exchange membranes are critically important for high temperature proton exchange membrane fuel cell (HT-PEMFC) operating between 100 and 200 °C. Herein, we demonstrate a novel ... -
Design, synthesis, and characterization of alpha,omega-disubstituted indeno[1,2-b]fluorene-6,12-dione-thiophene molecular semiconductors. Enhancement of ambipolar charge transport through synthetic tailoring of alkyl substituents
Ozdemir, Mehmet; Choi, Donghee; Kwon, Guhyun; Zorlu, Yunus; Kim, Hyekyoung; Kim, Myung-Gil; Seo, SungYong; Sen, Unal; Citir, Murat; Kim, Choongik; Usta, Hakan (ROYAL SOC CHEMISTRYTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND, 2016)A series of indeno[1,2-b]fluorene-6,12-dione-thiophene derivatives with hydrocarbon substituents at alpha,omega-positions as side groups have been designed and synthesized. The new compounds were fully characterized by ... -
Development of highly transparent Pd-coated Ag nanowire electrode for display and catalysis applications
Canlier, Ali; Ucak, Umit Volkan; Usta, Hakan; Cho, Changsoon; Lee, Jung-Yong; Sen, Unal; Citir, Murat (ELSEVIER, 2015)Ag nanowire transparent electrode has excellent transmittance (90%) and sheet resistance (20 Omega/sq), yet there are slight drawbacks such as optical haze and chemical instability against aerial oxidation. Chemical stability ... -
A dopant-free 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT)-based hole transporting layer for highly stable perovskite solar cells with efficiency over 22%
Kaya, Ismail Cihan; Ozdemir, Resul; Usta, Hakan; Sonmezoglu, Savas (ROYAL SOC CHEMISTRY, 2022)In this study, for the first time, n-i-p PSCs were fabricated using dopant-free 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT) as the solution-processed hole transporting layer (HTL). The power conversion ... -
Dynamic Tuning of Plasmonic Hot-Spot Generation through Cilia-Inspired Magnetic Actuators
Liman, Gorkem; Ergene, Emre; Yildiz, Emrecan; Hukum, Kubra Ozkan; Huri, Pinar Yilgor; Cetin, Arif E.; Usta, Hakan; Demirel, Gokhan (WILEY, 2023)Soft actuators that draw inspiration from nature are powerful and versatile tools for both technological applications and fundamental research, yet their use in hot-spot engineering is very limited. Conventional hot-spot ... -
Electrochemical polymerization of ambipolar carbonyl-functionalized indenofluorene with memristive properties
Figa, Viviana; Usta, Hakan; Macaluso, Roberto; Salzner, Ulrike; Ozdemir, Mehmet; Kulyk, Bohdan; Krupka, Oksana; Bruno, Maurizio (ELSEVIER, RADARWEG 29, 1043 NX AMSTERDAM, NETHERLANDS, 2019)Carbonyl-functionalized indenofluorene was electropolymerized with a high faradaic efficiency of 85% and the solid state properties of the resulting polymeric thin films were investigated. They displayed modular optical ... -
Enhanced mass transfer rate and solubility of methane via addition of alcohols for Methylosinus trichosporium OB3b fermentation
Kim, Kwangmin; Kim, Yujin; Yang, Jeongmo; Ha, Kyoung-Su; Usta, Hakan; Lee, Jinwon; Kim, Choongik (ELSEVIER SCIENCE INCSTE 800, 230 PARK AVE, NEW YORK, NY 10169, 2017)The effect of alcohol on methane-water volumetric mass transfer coefficient (1(0) and solubility of methane was investigated in this study. Various alcohols including methanol, ethanol, 1-propanol, butanol, and pentanol ... -
Enhancement of Anhydrous Proton Conductivity of Poly(vinylphosphonic acid)-Poly(2,5-benzimidazole) Membranes via In Situ Polymerization
Sen, Unal; Usta, Hakan; Acar, Oktay; Citir, Murat; Canlier, Ali; Bozkurt, Ayhan; Ata, Ali (WILEY-V C H VERLAG GMBH, 2015)Polymer electrolyte membranes (PEMs) are synthesized via in situ polymerization of vinylphosphonic acid (VPA) within a poly(2,5-benzimidazole) (ABPBI) matrix. The characterization of the membranes is carried out by using ... -
From 2-methylimidazole to 1,2,3-triazole: a topological transformation of ZIF-8 and ZIF-67 by post-synthetic modification
Erkartal, Mustafa; Erkilic, Ufuk; Tam, Benjamin; Yazaydin, Ozgur; Hupp, Joseph T.; Farha, Omar K.; Sen, Unal (ROYAL SOC CHEMISTRYTHOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND, 2017)Bridging ligand replacement in zeolitic imidazolate frameworks, ZIF-8 and ZIF-67, by 1,2,3-triazole was investigated. A complete substitution of 2-methylimidazole by 1,2,3-triazole resulted in a topological transformation ... -
The Hansen solubility approach towards green solvent processing: n-channel organic field-effect transistors under ambient conditions
Deneme, Ibrahim; Yıldız, Tevhide Ayça; Kayaci, Nilgun; Usta, Hakan (Royal Society of Chemistry, 2024)The adoption of green solvents is of utmost importance for the solution-based fabrication of semiconductor thin films and for the commercialization of (opto)electronic devices, especially in response to evolving regulatory ... -
High Electron Mobility in [1]Benzothieno[3,2-b][1]benzothiophene-Based Field-Effect Transistors: Toward n-Type BTBTs
Usta, Hakan; Kim, Dojeon; Ozdemir, Resul; Zorlu, Yunus; Kim, Sanghyo; Ruiz Delgado, M. Carmen; Harbuzaru, Alexandra; Kim, Seonhyoung; Demirel, Gokhan; Hong, Jongin; Ha, Young-Geun; Cho, Kilwon; Facchetti, Antonio; Kim, Myung-Gil (AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA, 2019)The first example of an n-type [1]benzothieno[3,2-b][1]benzothiophene (BTBT)-based semiconductor, D-(PhFCO)-BTBT, has been realized via a two-step transition metal-free process without using chromatographic purification. ... -
Highly Efficient Deep-Blue Electroluminescence Based on a Solution-Processable A-pi-D-pi-A Oligo(p-phenyleneethynylene) Small Molecule
Usta, Hakan; Alimli, Dilek; Ozdemir, Resul; Dabak, Salih; Zorlu, Yunus; Alkan, Fahri; Tekin, Emine; Can, Ayse (AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA, 2019)The development of solution-processable fluorescent small molecules with highly efficient deep-blue electroluminescence is of growing interest for organic light-emitting diode (OLED) applications. However, high-performance ... -
Indenofluorenes for organic optoelectronics: the dance of fused five- and six-membered rings enabling structural versatility
Can, Ayse; Facchetti, Antonio; Usta, Hakan (Royal Society of Chemistry, 2022)Polycyclic π-conjugated hydrocarbons (PCHs), either unfunctionalized or structurally modified derivatives, have attracted tremendous interest in the past few decades as high-performance semiconductors for use in new ... -
Logarithmic organic photodetectors
Elgazzar, Elsayed; Ozdemir, Mehmet; Usta, Hakan; Al-Ghamdi, Ahmed A.; DERE, Ayşegül; El-Tantawy, Farid; Yakuphanoglu, F. (ELSEVIER, 2015)A novel photodetector of Al/GO:C8-BTBT/n-Si/Au with various graphene oxide (GO) contents has been investigated. The electrical properties of the diodes were characterized by current–voltage (I–V) and capacitance–voltage ... -
Meso-pi-Extended/Deficient BODIPYs and Low-Band-Gap Donor-Acceptor Copolymers for Organic Optoelectronics
Can, Ayse; Choi, Gi-Seok; Ozdemir, Resul; Park, Soyoon; Park, Jin Su; Lee, Yongchul; Deneme, Ibrahim; Mutlugun, Evren; Kim, Choongik; Kim, Bumjoon J.; Usta, Hakan (AMER CHEMICAL SOC, 2022)The realization of π-deficient acceptors and their donor− acceptor copolymers has become a key research focus for the realization of versatile organic optoelectronic materials and devices. Herein, we demonstrate the ... -
Micro-/Nanostructured Highly Crystalline Organic Semiconductor Films for Surface-Enhanced Raman Spectroscopy Applications
Yilmaz, Mehmet; Ozdemir, Mehmet; Erdogan, Hakan; Tamer, Ugur; Sen, Unal; Facchetti, Antonio; Usta, Hakan; Demirel, Gokhan (WILEY-V C H VERLAG GMBH, 2015)The utilization of inorganic semiconductors for surface-enhanced Raman spectroscopy (SERS) has attracted enormous interest. However, despite the technological relevance of organic semiconductors for enabling inexpensive, ... -
Nanostructured organic semiconductor films for molecular detection with surface-enhanced Raman spectroscopy
Yilmaz, Mehmet; Babur, Esra; Ozdemir, Mehmet; Gieseking, Rebecca L.; Dede, Yavuz; Tamer, Ugur; Schatz, George C.; Facchetti, Antonio; Usta, Hakan; Demirel, Gokhan (NATURE RESEARCHHEIDELBERGER PLATZ 3, BERLIN 14197, GERMANY, 2017)pi-Conjugated organic semiconductors have been explored in several optoelectronic devices, yet their use in molecular detection as surface-enhanced Raman spectroscopy (SERS)-active platforms is unknown. Herein, we demonstrate ... -
Naphthalene diimide-based polymeric semiconductors. Effect of chlorine incorporation and n-channel transistors operating in water
Ryu, Gi-Seong; Chen, Zhihua; Usta, Hakan; Noh, Yong-Young; Facchetti, Antonio (MRS COMMUNICATIONS, 2016)We demonstrate here the design, synthesis and characterization of two new chlorinated polymers, P(NDI2HD-T2Cl2) and P(NDI2OD-T2Cl2) based on N,N-difunctionalized naphthalene diimide (NDI) and 3,3-dichloro-2,2-bithiophene ... -
Optimized Activation of Solution-Processed Amorphous Oxide Semiconductors for Flexible Transparent Conductive Electrodes
Choi, Byung Doo; Park, Joohyung; Baeg, Kang-Jun; Kang, Minji; Heo, Jae Sang; Kim, Seonhyoung; Won, Jongkook; Yu, Seungwoo; Ahn, Kyunghan; Lee, Tae Hoon; Hong, Jongin; Kim, Dong-Yu; Usta, Hakan; Kim, Choongik; Park, Sung Kyu; Kim, Myung-Gil (WILEY, 111 RIVER ST, HOBOKEN 07030-5774, NJ USA, 2018)Here, the preparation of transparent amorphous oxide semiconductor (AOS) films with unprecedented conductivity via an optimized activation process under hydrogen atmosphere for applications in solution-processed large-area ... -
Perfluoroalkyl-Functionalized Thiazole Thiophene Oligomers as N-Channel Semiconductors in Organic Field-Effect and Light-Emitting Transistors
Sheets, William Christopher; Denti, Mitchell; Generali, Gianluca; Capelli, Raffaella; Lu, Shaofeng; Yu, Xinge; Muccini, Michele; Facchetti, Antonio; Usta, Hakan (AMER CHEMICAL SOC, 2014)Despite their favorable electronic and structural properties, the synthetic development and incorporation of thiazole-based building blocks into n-type semiconductors has lagged behind that of other π-deficient building ...