Browsing by Author "Facchetti, Antonio"
Now showing items 1-19 of 19
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Design and development of functional organic small molecules and polymers for optoelectronics
Usta, Hakan; Demirel, Gokhan; Facchetti, Antonio; Muccini, Michele (AMER CHEMICAL SOC1155 16TH ST, NW, WASHINGTON, DC 20036 USA, 2016)Design and development of functional organic small molecules and polymers for optoelectronics -
High Electron Mobility in [1]Benzothieno[3,2-b][1]benzothiophene-Based Field-Effect Transistors: Toward n-Type BTBTs
Usta, Hakan; Kim, Dojeon; Ozdemir, Resul; Zorlu, Yunus; Kim, Sanghyo; Ruiz Delgado, M. Carmen; Harbuzaru, Alexandra; Kim, Seonhyoung; Demirel, Gokhan; Hong, Jongin; Ha, Young-Geun; Cho, Kilwon; Facchetti, Antonio; Kim, Myung-Gil (AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA, 2019)The first example of an n-type [1]benzothieno[3,2-b][1]benzothiophene (BTBT)-based semiconductor, D-(PhFCO)-BTBT, has been realized via a two-step transition metal-free process without using chromatographic purification. ... -
Indenofluorenes for organic optoelectronics: the dance of fused five- and six-membered rings enabling structural versatility
Can, Ayse; Facchetti, Antonio; Usta, Hakan (Royal Society of Chemistry, 2022)Polycyclic π-conjugated hydrocarbons (PCHs), either unfunctionalized or structurally modified derivatives, have attracted tremendous interest in the past few decades as high-performance semiconductors for use in new ... -
Insights Into Interface Treatments in p-Channel Organic Thin-Film Transistors Based on a Novel Molecular Semiconductor
Liguori, Rosalba; Usta, Hakan; Fusco, Sandra; Facchetti, Antonio; Licciardo, Gian Domenico; Di Benedetto, Luigi; Rubino, Alfredo (IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC445 HOES LANE, PISCATAWAY, NJ 08855-4141, 2017)Organic thin-film transistors (OTFTs) were fabricated using a novel small molecule, C6-NTTN, as the semiconductor layer in several different architectures. The C6-NTTN layer was deposited via both vacuum evaporation at ... -
Interplay between Charge Injection, Electron Transport, and Quantum Efficiency in Ambipolar Trilayer Organic Light-Emitting Transistors
Moschetto, Salvatore; Benvenuti, Emilia; Usta, Hakan; Özdemir, Resul; Facchetti, Antonio; Muccini, Michele; Prosa, Mario; Toffanin, Stefano (WILEY, 2022)The fascinating characteristic of organic light-emitting transistors (OLETs) of being electrical switches with an intrinsic light-emitting capability makes them attractive candidates for a wide variety of applications, ... -
Micro-/Nanostructured Highly Crystalline Organic Semiconductor Films for Surface-Enhanced Raman Spectroscopy Applications
Yilmaz, Mehmet; Ozdemir, Mehmet; Erdogan, Hakan; Tamer, Ugur; Sen, Unal; Facchetti, Antonio; Usta, Hakan; Demirel, Gokhan (WILEY-V C H VERLAG GMBH, 2015)The utilization of inorganic semiconductors for surface-enhanced Raman spectroscopy (SERS) has attracted enormous interest. However, despite the technological relevance of organic semiconductors for enabling inexpensive, ... -
Molecular engineering of organic semiconductors enables noble metal-comparable SERS enhancement and sensitivity
Demirel, Gokhan; Gieseking, Rebecca L. M.; Ozdemir, Resul; Kahmann, Simon; Loi, Maria A.; Schatz, George C.; Facchetti, Antonio; Usta, Hakan (NATURE PUBLISHING GROUP, MACMILLAN BUILDING, 4 CRINAN ST, LONDON N1 9XW, ENGLAND, 2019)Nanostructured molecular semiconductor films are promising Surface-Enhanced Raman Spectroscopy (SERS) platforms for both fundamental and technological research. Here, we report that a nanostructured film of the small ... -
Nanostructured organic semiconductor films for molecular detection with surface-enhanced Raman spectroscopy
Yilmaz, Mehmet; Babur, Esra; Ozdemir, Mehmet; Gieseking, Rebecca L.; Dede, Yavuz; Tamer, Ugur; Schatz, George C.; Facchetti, Antonio; Usta, Hakan; Demirel, Gokhan (NATURE RESEARCHHEIDELBERGER PLATZ 3, BERLIN 14197, GERMANY, 2017)pi-Conjugated organic semiconductors have been explored in several optoelectronic devices, yet their use in molecular detection as surface-enhanced Raman spectroscopy (SERS)-active platforms is unknown. Herein, we demonstrate ... -
Nanostructured superhydrophobic organic semiconductor films enable sub-zeptomole level molecular sensing in surface-enhanced Raman spectroscopy
Demirel, Gokhan; Usta, Hakan; Facchetti, Antonio (AMER CHEMICAL SOC1155 16TH ST, NW, WASHINGTON, DC 20036 USA, 2017)Nanostructured superhydrophobic organic semiconductor films enable sub-zeptomole level molecular sensing in surface-enhanced Raman spectroscopy -
Naphthalene diimide-based polymeric semiconductors. Effect of chlorine incorporation and n-channel transistors operating in water
Ryu, Gi-Seong; Chen, Zhihua; Usta, Hakan; Noh, Yong-Young; Facchetti, Antonio (MRS COMMUNICATIONS, 2016)We demonstrate here the design, synthesis and characterization of two new chlorinated polymers, P(NDI2HD-T2Cl2) and P(NDI2OD-T2Cl2) based on N,N-difunctionalized naphthalene diimide (NDI) and 3,3-dichloro-2,2-bithiophene ... -
Organic semiconductor based surface-enhanced Raman spectroscopy platforms
Demirel, Gokhan; Usta, Hakan; Facchetti, Antonio (AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA, 2018)Conference Conference: 256th National Meeting and Exposition of the American-Chemical-Society (ACS) - Nanoscience, Nanotechnology and Beyond Location: Boston, MA Date: AUG 19-23, 2018 Sponsor(s):Amer Chem Soc -
Paper-based substrates for sustainable (opto)electronic devices
Usta, Hakan; Facchetti, Antonio (ELSEVIER, 2022)Cellulose-based paper has been a convenient eco-friendly platform for storing and exchanging information for thousands of years. Amazingly, the studies and advancements in the past decade have demonstrated that paper and ... -
Perfluoroalkyl-Functionalized Thiazole Thiophene Oligomers as N-Channel Semiconductors in Organic Field-Effect and Light-Emitting Transistors
Sheets, William Christopher; Denti, Mitchell; Generali, Gianluca; Capelli, Raffaella; Lu, Shaofeng; Yu, Xinge; Muccini, Michele; Facchetti, Antonio; Usta, Hakan (AMER CHEMICAL SOC, 2014)Despite their favorable electronic and structural properties, the synthetic development and incorporation of thiazole-based building blocks into n-type semiconductors has lagged behind that of other π-deficient building ... -
Photosensing Properties of Pentacene OFETs Based on a Novel PMMA Copolymer Gate Dielectric
Loffredo, Fausta; GRIMALDI, IMMACOLATAANGELICA; Miscioscia, Riccardo; Nenna, Giuseppe; Villani, Fulvia; Minarini, Carla; Petrosino, Mario; Rubino, Alfredo; Usta, Hakan; Facchetti, Antonio (IEEE, 2015)In the present work, bottom-gate top-contact organic field effect transistors (OFETs) were fabricated by evaporating a pentacene semiconductor film on top of a new insulating poly(methyl methacrylate) (PMMA) copolymer ... -
pi-Conjugated donor-acceptor small molecule thin-films on gold electrodes for reducing the metal work-function
Azum, Naved; Taib, Layla Ahmad; Al Angari, Yasser Mohammed; Asiri, Abdullah M.; Denti, Mitchel; Zhao, Wei; Usta, Hakan; Facchetti, Antonio (ELSEVIER SCIENCE SAPO BOX 564, 1001 LAUSANNE, SWITZERLAND, 2016)This paper reports the design, facile synthesis and purification of four pi-conjugated donor-acceptor small molecules comprising heteroaromatic units, DA-1-DA-4, for surface and electronic structure modification of gold ... -
Polymeric and Small-Molecule Semiconductors for Organic Field-Effect Transistors
Usta, Hakan; Facchetti, Antonio (Wliey Online Library, 2015)This chapter reviews the achievements in the development of molecular and polymeric semiconductors for charge transport in thin-film transistors (TFTs). In particular, it introduces the basic concepts of organic semiconductor ... -
Selective Remanent Ambipolar Charge Transport in Polymeric Field-Effect Transistors For High-Performance Logic Circuits Fabricated in Ambient
Fabiano, Simone; Usta, Hakan; Forchheimer, Robert; Crispin, Xavier; Facchetti, Antonio; Berggren, Magnus (WILEY-V C H VERLAG GMBHPOSTFACH 101161, 69451 WEINHEIM, GERMANY, 2014)Ambipolar polymeric field-effect transistors can be programmed into a p- or n-type mode by using the remanent polarization of a ferroelectric gate insulator. Due to the remanent polarity, the device architecture is suited ... -
Solution-Processable BODIPY-Based Small Molecules for Semiconducting Microfibers in Organic Thin-Film Transistors
Ozdemir, Mehmet; Choi, Donghee; Kwon, Guhyun; Zorlu, Yunus; Cosut, Bunyemin; Kim, Hyekyoung; Facchetti, Antonio; Kim, Choongik; Usta, Hakan (AMER CHEMICAL SOC1155 16TH ST, NW, WASHINGTON, DC 20036, 2016)Electron-deficient pi-conjugated small molecules can function as electron-transporting semiconductors in various optoelectronic applications. Despite their unique structural, optical, and electronic properties, the development ... -
Ultrahigh Vacuum Self-Assembly of Rotationally Commensurate C8-BTBT/MoS2/Graphene Mixed-Dimensional Heterostructures
Liu, Xiaolong; Balla, Itamar; Sangwan, Vinod K.; Usta, Hakan; Facchetti, Antonio; Marks, Tobin J.; Hersam, Mark C. (AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA, 2019)Mixed-dimensional van der Waals heterostructures combine the advantages of nanomaterials with qualitatively distinct properties such as the extended bandstructures and high charge carrier mobilities of inorganic two-dimensional ...